Why Does the Rhodium-Catalyzed Hydrosilylation of Alkenes Take Place through a Modified Chalk−Harrod Mechanism? A Theoretical Study-Reference-Cited by-同舟云学术

Why Does the Rhodium-Catalyzed Hydrosilylation of Alkenes Take Place through a Modified Chalk−Harrod Mechanism? A Theoretical Study

Published:2002-08-07 Issue:18 Volume:21 Page:3788-3802
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Sakaki Shigeyoshi¹,Sumimoto Michinori¹,Fukuhara Mari¹,Sugimoto Manabu¹,Fujimoto Hitoshi¹,Matsuzaki Susumu¹

Affiliation:

1. Institute for Fundamental Research of Organic Chemistry, Kyushu University, Higashi-ku, Fukuoka 820-8581, Japan, Graduate School for Science and Technology, Kumamoto University, Kurokami, Kumamoto 860-8555, Japan, and Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, Kurokami, Kumamoto 860-8555, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om020239j

Reference57 articles.

1. For instance: (a) Speier, J. L.Adv. Organomet. Chem.1979,17, 407. (b) Harrod, J. F.; Chalk, A. J. InOrganic Synthesis via Metal Carbonyls; Wender, I., Pino, P., Eds.; John Wiley & Sons Ltd. New York, 1977; Vol. 2, p 673. (c) Tilley, T. D. InThe Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons Ltd. New York, 1989; p 1415. (d) Ojima, I. InThe Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons Ltd. New York, 1989; p 1479. (e) Ohsima, K. InAdvances in Metal-Organic Chemistry; Liebeskind, L. S., Ed.; JAI Press Ltd. London, 1991; Vol. 2, p 101.

2. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts

3. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part III. The Addition to Non-terminal Olefins in the Presence of Chloroplatinic Acid

4. The Addition of Silicon Hydrides to Olefinic Double Bonds. VIII. The Addition of Trichlorosilane-d

5. Homogeneous Catalysis. II. The Mechanism of the Hydrosilation of Olefins Catalyzed by Group VIII Metal Complexes1

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