Synthesis, Characterization, and Reactivity of Isocyanidephosphidoniobocene Derivatives: X-ray Diffraction Structures of New Isocyanideniobocene Complexes, [Nb(η5-C5H4SiMe3)2(CNR)(PMePh2)]I, R = Xylyl, Cy
Author:
Affiliation:
1. Departamento de Química Inorgánica, Orgánica y Bioquímica, Facultad de Química, Universidad de Castilla-La Mancha, 13071 Ciudad Real, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om060283p
Reference40 articles.
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2. Bonding interactions between three adjacent hydrogen ligands. Preparation and spectroscopic properties of the tantalum and niobium complexes [Ta(H)3(C5H5–nRn)2](R = SiMe3, n= 1 or 2) and [Nb(H3)(C5H5–nRn)2](n= 1, R = Me or SiMe3; n= 2, R = SiMe3)
3. Synthesis and Characterization of New Silyl Niobocene Complexes. X-ray Molecular Structure of d.degree. Nb(.eta.5-C5H4SiMe3)2(H)2(SiPh2H)
4. Studies of the reactivity towards insertion and electrophilic processes of Nb-H and Nb(η2-CS2) moieties of bis(trimethylsilylcyclopentadienyl)niobium complexes
5. Studies on the Insertion Reactions of Activated Alkynes into Nb−H Bonds in Hydride−Niobocene Complexes. X-ray Crystal Structures of Nb(η5-C5H4SiMe3)2(H)[η2-RO2C(H)C(H)CO2R] (R = Me or tBu)
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1. Cyclic and Non-Cyclic π-Complexes of Tantalum and Niobium;Comprehensive Organometallic Chemistry IV;2022
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