Orbital Overlap and Antiferromagnetic Coupling in Substituted Tetraphenylporphinatomanganate(III) Tetracyanoethenide Based Magnets. The Importance of σ−dz2−pz Overlap

Author:

Brandon Erik J.1,Kollmar Christian1,Miller Joel S.1

Affiliation:

1. Contribution from the Department of Chemistry, University of Utah, Salt Lake City, Utah 84112-0850, and the Physik Department, Theoretische Physik T38, Technische Universität München, James Franck Strasse, D-85748 Garching, Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference18 articles.

1. Manriquez, J. M.; Yee, G. T.; McLean, R. S.; Epstein, A. J.; Miller, J. S.Science1991,252, 1415. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J. Conjugated Polymers and Related Materials:  The Interconnection of Chemical and Electronic Structure. InThe Proceedings of Nobel Symposium#NS-81; Oxford University Press: Oxford, 1993; p 461;Chim.Ind.1992,74, 845. Epstein, A. J.; Miller, J. S. Conjugated Polymers and Related Materials:  The Interconnection of Chemical and Electronic Structure. InTheProceedings of Nobel Symposium #NS-81; Oxford University Press: Oxford, 1992; p 475;Chim.Ind.1993,75, 185. Zhang, J.; Zhou, P.; Brinckerhoff, W. B.; Epstein, A. J.; Vazquez, C.; McLean, R. S.; Miller, J. S.A.C.S. Sym. Ser.1996,644, 311.

2. Spontaneous magnetization in a 2:3 complex formed by 3,4′,5-tris(N-oxy-tert-butylamino)biphenyl and manganese(II)bis(hexafluoroacetylacetonate)

3. Relation between the singlet-triplet splitting and the copper-oxygen-copper bridge angle in hydroxo-bridged copper dimers

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