Ketone Super Silyl Enol Ethers in Sequential Reactions: Diastereoselective Generation of Tertiary Carbinols in One Pot-Reference-Cited by-同舟云学术

Ketone Super Silyl Enol Ethers in Sequential Reactions: Diastereoselective Generation of Tertiary Carbinols in One Pot

Published:2008-01-15 Issue:5 Volume:130 Page:1580-1582
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Boxer Matthew B.¹,Akakura Matsujiro¹,Yamamoto Hisashi¹

Affiliation:

1. Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, and Department of Chemistry, Aichi University of Education, Igaya-cho, Kariya 448-8542, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja7102586

Reference20 articles.

1. Asymmetric syntheses based on 1,3-oxathianes. 2. Synthesis of chiral tertiary .alpha.-hydroxy aldehydes, .alpha.-hydroxy acids, glycols [R1R2C(OH)CH2OH], and carbinols [R1R2C(OH)Me] in high enantiomeric purity.

2. Tris(trimethylsilyl)silyl-Governed Aldehyde Cross-Aldol Cascade Reaction

3. Triflimide (HNTf2)–catalyzed aldehyde cross-aldol reaction using “super silyl” enol ethers

4. “Super Silyl” Group for Diastereoselective Sequential Reactions: Access to Complex Chiral Architecture in One Pot

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