Rearranging Spin Electrons by Axial-Ligand-Induced Orbital Splitting to Regulate Enzymatic Activity of Single-Atom Nanozyme with Destructive d−π Conjugation

Author:

Zhao Qi1,Zhang Min1,Gao Yixuan1,Dong Hongliang2,Zheng Lirong3,Zhang Yutian1,Ouyang Jin4ORCID,Na Na1ORCID

Affiliation:

1. Key Laboratory of Radiopharmaceuticals, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, People’s Republic of China

2. Center for High Pressure Science and Technology Advanced Research, Shanghai 201203, People’s Republic of China

3. Beijing Synchrotron Radiation Facility Institute of High Energy Physics Chinese Academy of Sciences, Beijing 100049, People’s Republic of China

4. Department of Chemistry, College of Arts and Sciences, Beijing Normal University at Zhuhai, Zhuhai 519087, People’s Republic of China

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Key Project of Science and Technology Plan of Beijing Education Commission

Publisher

American Chemical Society (ACS)

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