Time-Resolved X-ray Emission Spectroscopy and Synthetic High-Spin Model Complexes Resolve Ambiguities in Excited-State Assignments of Transition-Metal Chromophores: A Case Study of Fe-Amido Complexes

Author:

Reinhard Marco E.1ORCID,Sidhu Baldeep K.2ORCID,Lozada Issiah B.2ORCID,Powers-Riggs Natalia3ORCID,Ortiz Robert J.2ORCID,Lim Hyeongtaek3ORCID,Nickel Rachel4ORCID,Lierop Johan van4,Alonso-Mori Roberto5ORCID,Chollet Matthieu5ORCID,Gee Leland B.5ORCID,Kramer Patrick L.5,Kroll Thomas1ORCID,Raj Sumana L.5ORCID,van Driel Tim B.5ORCID,Cordones Amy A.3ORCID,Sokaras Dimosthenis1,Herbert David E.2ORCID,Gaffney Kelly J.3ORCID

Affiliation:

1. Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States

2. Department of Chemistry and the Manitoba Institute for Materials, University of Manitoba, 144 Dysart Rd, Winnipeg, Manitoba R3T 2N2, Canada

3. Stanford PULSE Institute, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States

4. Department of Physics and Astronomy, University of Manitoba, 31A Sifton Rd, Winnipeg, Manitoba R3T 2N2, Canada

5. Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States

Funder

Basic Energy Sciences

Natural Sciences and Engineering Research Council of Canada

Publisher

American Chemical Society (ACS)

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