Ethylene Ligand Structures of Os(CO)4(C2H4) and Os2(CO)8(C2H4) Determined by 1H NMR in Liquid Crystal Solvents
Author:
Affiliation:
1. Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523
2. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia V6T 1Z1, Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic971637v
Reference51 articles.
1. Reversible stereospecific extrusion of ethylene from a 1,2-diosmacyclobutane. Determination of stereochemistry by liquid-crystal NMR
2. Retention of Stereochemistry in the Formation and Fragmentation of Diosmacyclobutanes, and Other Evidence against a Diradical Mechanism
3. Vibrational Spectroscopic Studies of the Structure of Species Derived From the Chemisorption of Hydrocarbons on Metal Single-Crystal Surfaces
4. [Os2(CO)8(µ2-η2-C2H4)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces
5. [(? 2-C2H4)Os(CO)4] as a vibrational model for type I? ethene chemisorbed as a metallacyclopropane on metal surfaces
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1. Ethylene Substitution in a Bis-Ethylene Complex of Rh/Os and Unusual Brønsted−Lowry Basicity of an N-Heterocyclic Carbene;Organometallics;2011-01-25
2. Structure of Tetracarbonylethyleneosmium: Ethylene Structure Changes upon Complex Formation;Journal of the American Chemical Society;2007-08-01
3. Mononuclear Ru/Os Compounds with Hydrocarbon Ligands: Compounds with η2–η4 Ligands;Comprehensive Organometallic Chemistry III;2007
4. A vibrational study of the diosmacyclobutene complex Os2(CO)8(μ2–η1,η1–C2H2): The use of organometallic complexes as vibrational models for chemisorbed ethyne;Phys. Chem. Chem. Phys.;2004
5. [Os2(CO)8(μ2-η1,η1-propene)] and Related Complexes as Vibrational Models for Alkenes Chemisorbed on Single-Crystal Metal Surfaces;Journal of the American Chemical Society;1999-01-01
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