Silyl Substitution Effects on Metal−Pentadienyl Bonding: Synthesis, Structure, Photoelectron Spectroscopy, and Electronic Structure of a High-Valent Half-Open Zirconocene-Reference-Cited by-同舟云学术

Silyl Substitution Effects on Metal−Pentadienyl Bonding: Synthesis, Structure, Photoelectron Spectroscopy, and Electronic Structure of a High-Valent Half-Open Zirconocene

Published:2007-04-21 Issue:11 Volume:26 Page:2867-2871
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Rajapakshe Asha¹,Basta Rehan¹,Arif Atta M.¹,Ernst Richard D.¹,Lichtenberger Dennis L.¹

Affiliation:

1. Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850, and Department of Chemistry, The University of Arizona, Tucson, Arizona 85721

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om070008i

Reference41 articles.

1. Pentadienyl Ligands: Their Properties, Potential, and Contributions to Inorganic and Organometallic Chemistry

2. Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me3C6H2)2C6H3N]2- ([Ar*N]2-). Generation and Reactivity of [(Ar*N)(Ar*NH)Ta(H)(OSO2CF3)], Which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand

3. Reversible Intramolecular Hydride Transfer between Tantalum and an Aromatic Ring: An η5-Cyclohexadienyl Complex as a Masked Hydride

4. Low-Valent Tungsten Aryloxide Compounds with Pyridine Ancillary Ligation: Intramolecular Reduction of Heterocyclic and Aromatic Rings Including Formation of an η5-Cyclohexadienyl Group

5. t-Butylimido and t-butylimido oxo aryls of rhenium. X-ray crystal structures of Re(NBut)2(2,6-Me2C6H3)2, Re(NBut)(2,4,6-Me3C6H2)(C27H32), Re(NBut)3(2,4,6-Me3C6H2), [(ButN)Br(2,4,6-Me3C6H2)Re(μ-NBut)(μ-O)(OC6H2Me2CH2)(NBut)], [Re(NBut)(O)Ar(μ-O)]2, Ar = 2,6-C6H3 and 2,4,6-C6H2

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