Lithiation of TMEDA and its Higher Homologous TEEDA: Understanding Observed α- and β-Deprotonation
Author:
Affiliation:
1. Anorganische Chemie, Technische Universität Dortmund, Otto-Hahn-Str. 6, 44227 Dortmund, Germany
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja8058205
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1. Lithium-Mediated Zincation of Pyrazine, Pyridazine, Pyrimidine, and Quinoxaline
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3. Ortholithiation of Anisole by n-BuLi−TMEDA: Reaction via Disolvated Dimers
4. Complex-induced proximity effects and dipole-stabilized carbanions: kinetic evidence for the role of complexes in the .alpha.'-lithiations of carboxamides
5. Stereoselectivity of cyclization of substituted 5-hexen-1-yllithiums: regiospecific and highly stereoselective insertion of an unactivated alkene into a carbon-lithium bond
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