Silylstannylation of Highly Functionalized Acetylenes. Synthesis of Precursors for Annulations via Radical or Heck Reactions
Author:
Affiliation:
1. Department of Chemistry, The Ohio State University, Columbus, Ohio 43210
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol048265w
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1. First Demonstration of Helical Chirality in 1,4-Disubstituted (Z,Z)-1,3-Dienes: R3Si−SnR‘3-Mediated Cyclization of 1,6-Diynes
2. Axial Chirality in 1,4-Disubstituted (ZZ)-1,3-Dienes. Surprisingly Low Energies of Activation for the Enantiomerization in Synthetically Useful Fluxional Molecules
3. Silyl stannanes: useful reagents for bis-functionalization of .alpha.,.beta.-unsaturated ketones and acetylenes
4. Palladium-Catalyzed Bismetallative Cyclization of Enynes
5. N-Trimethylsilylimines: applications to the syntheses of .beta.-lactams
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