Temperature Dependence of the Rate Constants and Branching Ratios for the Reactions of Cl-(D2O)1-3 with CH3Br and Thermal Dissociation Rates for Cl-(CH3Br)
Author:
Affiliation:
1. Contribution from Phillips Laboratory, Geophysics Directorate, Ionospheric Effects Division (GPID), 29 Randolph Road, Hanscom AFB, Massachusetts 01731-3010, and Department of Chemistry, Wayne State University, Detroit, Michigan 48202
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja960872u
Reference69 articles.
1. Temperature dependence of the kinetic isotope effect for a gas-phase SN2 reaction: Cl- + CH3Br
2. Kinetics of the gas-phase reactions of chloride anion, Cl- with CH3Br and CD3Br: experimental evidence for nonstatistical behavior?
3. The nonstatistical dissociation dynamics of chloride(bromomethane) Cl-(CH3Br): evidence for vibrational excitation in the products of gas-phase SN2 reactions
4. Gas-phase SN2 reactions of chloride ion with alkyl bromides at atmospheric pressure. Temperature dependence of the rate constants and energies of the transition states
5. Collisional activation of captured intermediates in the gas-phase SN2 reaction chloride + bromomethane .fwdarw. bromide + chloromethane
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