Substituent and Solvent Effects on the Photosensitized Oxygenation of 5,6-Dihydro-1,4-oxathiins. Intramolecular Oxygen Transfer vs Normal Cleavage of the Dioxetane Intermediates

Author:

Cermola F.1,Iesce M. R.1

Affiliation:

1. Dipartimento di Chimica Organica e Biochimica, Università degli Studi di Napoli Federico II, Complesso Universitario di Monte Sant'Angelo, via Cinthia, I-80126 Napoli, Italy

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference38 articles.

1. (a) Foote, C. S.; Clennan, E. L. InActive Oxygen in Chemistry; Foote, C. S., Valentine, J. S., Greenberg, A., Liebman, J. F., Eds.; Chapman and Hall:  London, 1995; p 105.

2. (c) Schaap, A. P.; Zaklika, K. A. InSinglet Oxygen; Wasserman, H. H., Murray, R. W., Eds.; Academic Press:  New York, 1979; p 234.

3. Dye-sensitized photooxygenation of 2,3-dihydrothiophenes: formation of stable 1,2-dioxetanes from 4,5-dialkyl-substituted derivatives

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