Dinitrogen Activation at Ambient Temperatures: New Modes of H2 and PhSiH3 Additions for an “End-On-Bridged” [Ta(IV)]2(μ-η:η1-N2) Complex and for the Bis(μ-nitrido) [Ta(V)(μ-N)]2 Product Derived from Facile N⋮N Bond Cleavage
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja072248v
Reference8 articles.
1. Multimetallic Cooperative Activation of N2
2. Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex
3. N2 Cleavage by Three-Coordinate Group 6 Complexes. W(III) Complexes Would Be Better Than Mo(III) Complexes
4. Tantalum complexes containing diimido bridging dinitrogen ligands
5. Thiolato dinitrogen (or hydrazido(4-)) complexes, [Ta(SAr)3(THF)]2(.mu.-N2) (Ar = 2,6-C6H3-iso-Pr2, 2,4,6-C6H2-iso-Pr3), and phenoxide analogs. A structural comparison of [Ta(S-2,6-C6H3-iso-Pr2)3(THF)]2(.mu.-N2), and [Ta(O-2,6-C6H3-iso-Pr2)3(THF)]2(.mu.-N2)
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