Synthesis, Spectroscopic Characterization, and Reactivity of the Unusual Five-Coordinate Hydrido−Vinylidene Complex OsHCl(CCHPh)(PiPr3)2: Precursor for Dioxygen Activation-Reference-Cited by-同舟云学术

Synthesis, Spectroscopic Characterization, and Reactivity of the Unusual Five-Coordinate Hydrido−Vinylidene Complex OsHCl(CCHPh)(PiPr3)2: Precursor for Dioxygen Activation

Published:1997-02-01 Issue:4 Volume:16 Page:636-645
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Bourgault Manuel¹,Castillo Amaya¹,Esteruelas Miguel A.¹,Oñate Enrique¹,Ruiz Natividad¹

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-Consejo Superior de Investigaciones Científicas, 50009 Zaragoza, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om960525t

Reference77 articles.

1. Five- and six-coordinate hydrido(carbonyl)-ruthenium(II) and -osmium(II) complexes containing triisopropylphosphine as ligand

2. MHCl(CO)(PiPr3)2 (M = Ru, Os) complexes as catalyst precursors for the reduction of unsaturated substrates

3. Kinetic and mechanistic investigation of the sequential hydrogenation of phenylacetylene catalyzed by OsHCl(CO)(PR3)2 [PR3 = PMe-tert-Bu2 and P-i-Pr3]

4. The reduction of α,β-unsaturated ketones and cyclohexadienes catalyzed by mhcl(CO)(PiPr3)2 (M = Ru, Os) complexes

5. Insertion reaction of acetone-d6 into the osmium-hydrogen bond of [OsHCl(CO)(P-iso-Pr3)2]: experimental evidence for the hydrogen-transfer mechanism from alcohols to ketones

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