Solid-State and Solution Rearrangements of F3S≡NXeF+ Leading to the F4S═NXe+ Cation; Syntheses, HF Solvolyses, and Structural Characterizations of [F4S═NXe][AsF6] and [F4S═NH2][AsF6]-Reference-Cited by-同舟云学术

Solid-State and Solution Rearrangements of F3S≡NXeF+ Leading to the F4S═NXe+ Cation; Syntheses, HF Solvolyses, and Structural Characterizations of [F4S═NXe][AsF6] and [F4S═NH2][AsF6]

Published:2009-05-11 Issue:21 Volume:131 Page:7272-7286
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Smith Gregory L.¹,Mercier Hélène P. A.¹,Schrobilgen Gary J.¹

Affiliation:

1. Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja901187n

Reference64 articles.

1. Synthesis of [F3S⋮NXeF][AsF6] and Structural Study by Multi-NMR and Raman Spectroscopy, Electronic Structure Calculations, and X-ray Crystallography

2. Fluoro(nitrile)xenon(II) cations, RCN–XeF+AsF6–(R = H, CH3, CH2F, C2H5, C2F5, C3F7, or C6F5); novel examples of xenon–nitrogen bonds and129Xe–13C,129Xe–1H, and129Xe-14N nuclear spin-spin couplings

3. The fluoro(hydrogen cyanide)xenon(II) cation. Preparation of HC.tplbond.NXeF+AsF6-: a multinuclear magnetic resonance and Raman spectroscopic study

4. The fluoro(perfluoroalkylnitrile)noble-gas(II) cations, RFCN–NgF+(Ng = Kr or Xe; RF= CF3, C2F5, n-C3F7), and the fluoro(trifluoro-s-triazine)xenon(II) cation, s-C3F3N2N–XeF+; novel noble gas–nitrogen bonds

5. The fluoro(perfluoropyridine)xenon(II) cations, C5F5N–XeF+and 4-CF3C5F4N–XeF+; novel examples of xenon as an aromatic substituent and of xenon–nitrogen bonding

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