How Do Nitriles Compare with Isoelectronic Alkynyl Groups in the Electronic Communication between Iron Centers Bridged by Phenylenebis- and -tris(nitrile) Ligands? An Electronic and Crystal-Structure Study

Author:

Bonniard Lauréline12,Kahlal Samia12,Diallo Abdou K.3,Ornelas Cátia3,Roisnel Thierry12,Manca Gabriele12,Rodrigues João4,Ruiz Jaime3,Astruc Didier3,Saillard Jean-Yves12

Affiliation:

1. Sciences Chimiques de Rennes, UMR CNRS No. 6226, Université de Rennes 1, 35042 Rennes Cedex, France

2. Université Européenne de Bretagne, 5 bd Laënnec, 35000 Rennes, France

3. Institut des Sciences Moléculaires, UMR CNRS No. 5255, Université Bordeaux 1, 351 Cours de la Libération, 33405 Talence Cedex, France

4. CQM-Centro de Química da Madeira, LQCMM/MMRG, Universidade da Madeira, Campus Universitário da Penteada, 9000-390 Funchal, Portugal

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference66 articles.

1. Organonitrile complexes of transition metals

2. cEndres, H. I. P.InComprehensive Coordination Chemistry;Wilkinson, G. and Gillard, J. A., Eds.Pergamon:Oxford, U.K., 1987; Vol.2, p261.

3. Reactions of transition metal-coordinated nitriles

4. Monomeric and dimeric ruthenium-TCNQ complexes containing phosphine ligands (TCNQ = 7,7,8,8-tetracyanoquinodimethane)

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