Synthesis and Characterization of RuH2(H2)2(PiPr3)2 and Related Chemistry. Evidence for a Bis(dihydrogen) Structure
Author:
Affiliation:
1. Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om990669i
Reference53 articles.
1. Photolysis of hexacarbonylchromium in hydrogen-containing matrixes: evidence of simple adducts of molecular hydrogen
2. Structure and thermal reactions of dihydrogen complexes: the IR characterization of M(CO)5(H2) (M = chromium, molybdenum, and tungsten) and cis-Cr(CO)4(H2)2 in liquid xenon solution and the formation of HD during exchange of hydrogen and deuterium
3. Monomeric and dimeric ruthenium(II) .eta.2-dihydrogen complexes with tricyclohexylphosphine co-ligands
4. Versatile Reactivity of the Bis(dihydrogen) Complex RuH2(H2)2(PCy3)2 toward Functionalized Olefins: Olefin Coordination versus Hydrogen Transfer via the Stepwise Dehydrogenation of the Phosphine Ligand
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