Solvent Choice Differentiates SET-LRP and Cu-Mediated Radical Polymerization with Non-First-Order Kinetics
Author:
Affiliation:
1. Roy & Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ma801774d
Reference16 articles.
1. Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C
2. A comparative analysis of SET-LRP of MA in solvents mediating different degrees of disproportionation of Cu(I)Br
3. Ultrafast SET-LRP of methyl acrylate at 25 °C in alcohols
4. Aqueous Room Temperature Metal-Catalyzed Living Radical Polymerization of Vinyl Chloride
5. Living radical polymerization of vinyl chloride initiated with iodoform and catalyzed by nascent Cu0/tris(2-aminoethyl)amine or polyethyleneimine in water at 25 °C proceeds by a new competing pathways mechanism
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