Iridium-Catalyzed Regio- and Enantioselective Allylation of Ketone Enolates

Author:

Graening Timm1,Hartwig John F.1

Affiliation:

1. Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference23 articles.

1. (a) Negishi, E.I.; Liou, S.Y. InHandbook of Organopalladium Chemistry forOrganic Synthesis; Negishi, E., Ed.; John Wiley:  New York, 2002; Vol. 2, p 1769. For enantioselective additions of malonate-type nucleophiles to the more substituted terminus of allylic substrates, using metals other than palladium, see:  (b) Trost, B. M.; Hachiya, I.J. Am. Chem. Soc.1998,120, 1104.

2. Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands

3. Chiral Phosphanodihydrooxazoles in Asymmetric Catalysis: Tungsten-Catalyzed Allylic Substitution

4. Ir-catalysed allylic substitution: mechanistic aspects and asymmetric synthesis with phosphorus amidites as ligands

5. Enantioselective allylic substitution catalyzed by an iridium complex: remarkable effects of the counter cation

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