Alkene and Alkyne Reactivity Toward a Bisruthenium(II) μ2-Dinitrogen Complex Containing the “Pincer” Ligand 2,6-Bis[(dimethylamino)methyl]pyridine (NN‘N). The X-ray Crystal Structures of [Ru(CCHPh)Cl2(NN‘N)] and [Ru(CCHPh)(OTf)(NN‘N)(PPh3)][OTf] (OTf = Trifluoromethane Sulfonate)-Reference-Cited by-同舟云学术

Alkene and Alkyne Reactivity Toward a Bisruthenium(II) μ2-Dinitrogen Complex Containing the “Pincer” Ligand 2,6-Bis[(dimethylamino)methyl]pyridine (NN‘N). The X-ray Crystal Structures of [Ru(CCHPh)Cl2(NN‘N)] and [Ru(CCHPh)(OTf)(NN‘N)(PPh3)][OTf] (OTf = Trifluoromethane Sulfonate)

Published:1999-02-24 Issue:6 Volume:18 Page:1097-1105
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

del Río Ignacio¹,Gossage Robert A.¹,Hannu Milja S.¹,Lutz Martin¹,Spek Anthony L.¹,van Koten Gerard¹

Affiliation:

1. Debye Institute, Department of Metal-Mediated Synthesis, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands, and Bijvoet Center for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om980878n

Reference57 articles.

1. Organometallic chemistry of vinylidene and related unsaturated carbenes

2. Regio- and Stereoselective Dimerization of Phenylacetylene to (Z)-1,4-Diphenylbut-3-en-1-yne by Ruthenium(II) Catalysis. Reaction Mechanism Involving Intermolecular Protonation of .sigma.-Alkynyl by 1-Alkyne

3. Homogeneous Catalytic Dimerization of Terminal Alkynes by C5Me5Ru(L)H3 (L = PPh3, PCy3, PMe3)

4. Palladium-Catalyzed Additions of Terminal Alkynes to Acceptor Alkynes

5. Stoichiometric alkyne cyclotrimerization at a ruthenium centre: A new synthetic route to Ru(η6-arene)(η4-cycloocta-1,5-diene) complexes

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