Internal Fluorocarbon Coordination as a Tool for the Protection of Active Catalytic Sites: Experimental Characterization of the Zr···F−C Interaction in the Group 4 Metallocene(butadiene)/B(C6F5)3 Betaine Ziegler Catalyst Systems
Author:
Affiliation:
1. Contribution from the Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, D-48149 Münster, Germany
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja971720h
Reference39 articles.
1. Ziegler-Natta Catalysis
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3. Zirconium-catalyzed coupling of propene and .alpha.-picoline
4. Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentafluorophenyl)borane. A Synthetic,Structural, Solution Dynamic, and Polymerization Catalytic Study
5. Formation of ion pairs in the Ziegler ethylene polymerization catalyst system Cp2Ti(Cl)CH2SiMe3-AlCl3
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