Preparation, Structures, and Some Reactivities of Five-Coordinate Alkyne Complexes of Mo with Tetraphosphine or Diphosphine Coligand [Mo(RC≡CR′){meso-o-C6H4(PPhCH2CH2PPh2)2}] and [Mo(RC≡CR′)(Ph2PCH2CH2PPh2)2]-Reference-Cited by-同舟云学术

Preparation, Structures, and Some Reactivities of Five-Coordinate Alkyne Complexes of Mo with Tetraphosphine or Diphosphine Coligand [Mo(RC≡CR′){meso-o-C6H4(PPhCH2CH2PPh2)2}] and [Mo(RC≡CR′)(Ph2PCH2CH2PPh2)2]

Published:2009-01-26 Issue:4 Volume:28 Page:1112-1121
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Niikura Fumiya¹,Seino Hidetake¹,Mizobe Yasushi¹

Affiliation:

1. Institute of Industrial Science, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8505, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om800615a

Reference52 articles.

1. Formation of Novel Tetradentate Phosphine Ligando-C6H4(PPhCH2CH2PPh2)2by Coupling of Two Diphosphine Ligands Bound to Low-Valent Mo or W Center. Synthesis and Structure of [M{o-C6H4(PPhCH2CH2PPh2)2}(Ph2PCH2CH2PPh2)] (M = Mo, W)

2. Preparation of Mo and W Complexes Containing a New Linear Tetradentate Phosphine Ligandmeso-o-C6H4(PPhCH2CH2PPh2)2from Dinitrogen Complexestrans-[M(N2)2(Ph2PCH2CH2PPh2)2] (M = Mo, W)

3. Reactions of tetraphosphine complex [Mo{meso-o-C6H4(PPhCH2CH2PPh2)2}(Ph2PCH2CH2PPh2)] with nitrile, CO, and isocyanide

4. The CO and CS bond cleavage in carbon dioxide and tolyl isothiocyanate by reactions with the Mo(0) tetraphosphine complex [Mo{meso-o-C6H4(PPhCH2CH2PPh2)2}(Ph2PCH2CH2PPh2)]

5. Mo and W Dihalide Complexes with Uncommon Trigonal-Prismatic Geometry Imposed by the Linear Tetraphosphine Ancillary Ligand and Their Reactivities toward Diazoalkanes

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