Metalation of Trimethylphosphine−Borane. Unexpected Reactivity of a Simple Phosphine−Borane-Stabilized Carbanion toward Siloxanes

Author:

Izod Keith1,Wills Corinne1,Clegg William1,Harrington Ross W.1

Affiliation:

1. Main Group Chemistry Laboratories, Department of Chemistry, School of Natural Sciences, Bedson Building, University of Newcastle, Newcastle upon Tyne, NE1 7RU, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference41 articles.

1. For recent reviews see:  (a) Ohf, M.; Holz, J.; Quirmbach, M.; Borner, A.Synthesis1998, 1391. (b) Brunel, J. M.; Faure, B.; Maffei, M.Coord.Chem. Rev.1998,178−180, 665. (c) Carboni, B.; Monnier, L.Tetrahedron1999,55, 1197. (d) Paine, R. T.; Nöth, H.Chem. Rev.1995,95, 343. (e) Gaumont, A. C.; Carboni, B. InScience of Synthesis; Kaufmann, D., Matteson, D. S., Eds.; Thieme:  Stuttgart, 2004; Vol. 6, pp 485−512.

2. Enantioselective Deprotonation as a Vehicle for the Asymmetric Synthesis of C2-Symmetric P-Chiral Diphosphines

3. Synthesis and Crystal Stucture of a Salt Containing the Anion; Precursors and Related Compounds

4. Synthesis of a New Chiral Source, (1R,2S)-1-Phenylphospholane-2-carboxylic Acid, via a Key Intermediate ?-Phenylphospholanyllithium Borane Complex: Configurational Stability and X-ray Crystal Structure of an ?-Monophosphinoalkyllithium Borane Complex

5. Synthesis and structural characterisation of a novel phosphine-borane-stabilised dicarbanion and an unusual bis(phosphine-borane)

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