Bridgehead Carbocations via Carbene Fragmentation: Erasing a 1010 Kinetic Preference-Reference-Cited by-同舟云学术

Bridgehead Carbocations via Carbene Fragmentation: Erasing a 1010 Kinetic Preference

Published:2002-04-18 Issue:19 Volume:124 Page:5258-5259
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Moss Robert A.¹,Zheng Fengmei¹,Fedé Jean-Marie¹,Ma Yan¹,Sauers Ronald R.¹,Toscano John P.¹,Showalter Brett M.¹

Affiliation:

1. Department of Chemistry and Chemical Biology, Rutgers, the State University of New Jersey, New Brunswick, New Jersey 08903 and Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja020002e

Reference24 articles.

1. (a) Lowry, T. H.; Richardson, K. S.Mechanism and Theory in OrganicChemistry, 3rd ed.; Harper and Row: New York, 1987; pp 391−393.

2. (b) Carey, F. A.; Sundberg, R. J.Advanced Organic Chemistry, Part A: Structure and Mechanism, 4th ed.; Kluwer Academic/Plenum: New York, 2000; pp 287−289.

3. krel(X = OTs):1a1(10-10),2(10-4),3(1.0); (X = Br):1b1(10-10),2(10-3),3(1.0).

4. Calculation of bridgehead reactivities

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