Synthesis and Reactions of Five-Coordinate Mono- and Binuclear Thiocarbonyl−Alkenyl and Thioacyl Complexes of Ruthenium(II)-Reference-Cited by-同舟云学术

Synthesis and Reactions of Five-Coordinate Mono- and Binuclear Thiocarbonyl−Alkenyl and Thioacyl Complexes of Ruthenium(II)

Published:2007-11-07 Issue:25 Volume:26 Page:6114-6125
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Cowley Andrew R.¹,Hector Andrew L.¹,Hill Anthony F.¹,White Andrew J. P.¹,Williams David J.¹,Wilton-Ely James D. E. T.¹

Affiliation:

1. Chemistry Research Laboratory, University of Oxford, Oxford, U.K., Department of Chemistry, Imperial College, London, U.K., and Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, Australian Capital Territory, Australia

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om700518m

Reference95 articles.

1. Insertion reactions of acetylenes with hydridocarbonyl-chlorotris(triphenylphosphine)ruthenium(II). X-ray structure of carbonylchloro(cis-1,2-diphenylethenyl)bis(triphenylphosphine)ruthenium(II)

2. Reactions of [Ru(CO)ClH(Me2Hpz)(PR3)2] (Me2Hpz = 3,5-dimethylpyrazole; R = Ph, p-tolyl) with acetylenes. The crystal structure of [Ru(CO)Cl(HC:CHCMe3)(Me2HPz)(PPh3)2] and [Ru(CO)(MeO2CC:CHCO2Me)(HCO3)(PPh3)2]

3. Reactions of Ru(CO)Cl(RCCHR′)(PPh3)2 with carboxylates. The crystal structure of Ru(O2CMe)(CO)(HCCHPh)(PPh3)2

4. Reaction of Ru(CO)Cl(RCCHR′)(PPh3)2 with the 3,3-dimethylacrylate anion. The molecular structure of Ru(O2CCHCMe2)(CO)(C(CO2Me)CH(CO2Me))(PPh3)2

5. Reaction of alkenyl carbonyl ruthenium(II) complexes with t-butyl isocyanide. Synthesis of η1-acylruthenium(II) complexes by intramolecular CO insertion

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