Synthesis and Reactivity of Tantalum Alkylidene Complexes Containing the C,N,N‘-Chelating Aryldiamine Ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]- (CNN). X-ray Structures of [TaCl2(CH-t-Bu)(CNN)], [Ta{(CH2)3-1,3}(CNN)(O-t-Bu)2], and [Ta(CNN)(O-t-Bu)2(H2CCH2)]-Reference-Cited by-同舟云学术

Published:1997-04-01 Issue:8 Volume:16 Page:1674-1684
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Rietveld Marco H. P.¹,Teunissen Wendy¹,Hagen Henk¹,van de Water Leon¹,Grove David M.¹,van der Schaaf Paul A.¹,Mühlebach Andreas¹,Kooijman Huub¹,Smeets Wilberth J. J.¹,Veldman Nora¹,Spek Anthony L.¹,van Koten Gerard¹

Affiliation:

1. Debye Institute, Department of Metal-Mediated Synthesis, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands, Ciba-Geigy Limited, Materials Research, CH-1723 Marly, Switzerland, and Bijvoet Center for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9606799

Reference53 articles.

1. Use of an aryldiamine pincer ligand in the study of tantalum alkylidene-centered reactivity: tantalum-mediated alkene synthesis via reductive rearrangements and Wittig-type reactions

2. Configurational Preferences and Alkylidene-Centered Reactivity of Tantalum Alkoxide Complexes Containing an Aryldiamine Spectator Ligand

3. Effect of Intramolecular Coordination on Tantalum-Alkylidene-Centered Reactions: Synthesis and Structure of a Tantalum-Olefin Adduct and a Tantalum-Zinc-Alkylidene Complex

4. Rigid five- and six-membered C,N,N'-bound aryl-, benzyl-, and alkylorganopalladium complexes: sp2 vs. sp3 carbon-hydrogen activation during cyclopalladation and palladium(IV) intermediates in oxidative addition reactions with dihalogens and alkyl halides

5. Ligand substitution reactions in new square-planar iridium, rhodium and platinum complexes containing a potentially terdentate C,N,N′ ligand system; crystal structure of [Ir{C6H4CH2N(Me)CH2CH2NMe2-2-C,N,N′}(cod)](cod = cycloocta-1,5-diene)

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