Involvement of a Binuclear Species with the Re−C(O)O−Re Moiety in CO2 Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands:  Strikingly Slow Formation of the Re−Re and Re−C(O)O−Re Species from Re(dmb)(CO)3S (dmb = 4,4‘-Dimethyl-2,2‘-bipyridine, S = Solvent)

Author:

Hayashi Yukiko1,Kita Shouichi1,Brunschwig Bruce S.1,Fujita Etsuko1

Affiliation:

1. Contribution from the Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973-5000

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference69 articles.

1. Photo-Induced Generation of Dihydrogen and Reduction of Carbon Dioxide Using Transition Metal Complexes

2. Fujita, E.; Brunschwig, B. S. InCatalysis of Electron Transfer,Heterogeneous and Gas-Phase Systems; Fukuzumi, S., Mallouk, T. E., Haas, Y., Eds.; Wiley-VCH:  Weinheim, Germany, 2001; Vol. 4, pp 88−126.

3. Photochemical and Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide Mediated by (2,2?-Bipyridine)tricarbonylchlororhenium(I) and Related Complexes as Homogeneous Catalysts

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