Substrate and Lewis Acid Coordination Promote O–O Bond Cleavage of an Unreactive L2CuII2(O22–) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity-Reference-Cited by-同舟云学术

Substrate and Lewis Acid Coordination Promote O–O Bond Cleavage of an Unreactive L2CuII2(O22–) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity

Published:2017-02-14 Issue:8 Volume:139 Page:3186-3195
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Garcia-Bosch Isaac¹,Cowley Ryan E.²,Díaz Daniel E.³,Peterson Ryan L.³,Solomon Edward I.²,Karlin Kenneth D.³^ORCID

Affiliation:

1. Department of Chemistry, Southern Methodist University, Dallas, Texas 75275, United States

2. Department of Chemistry, Stanford University, Stanford, California 94305, United States

3. Johns Hopkins University, Baltimore, Maryland 21218, United States

Funder

Welch Foundation

National Institute of Diabetes and Digestive and Kidney Diseases

National Institute of General Medical Sciences

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.6b12990

Reference55 articles.

1. Copper Active Sites in Biology

2. Tyrosinase versus Catechol Oxidase: One Asparagine Makes the Difference

3. The First Crystal Structure of Tyrosinase: All Questions Answered?

4. Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism

5. Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models

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