Doubly Diastereoconvergent Preparation and Microsolvation-Controlled Properties of (Z)- and (E)-1′-Lithio-1′-(2,6-dimethylphenyl)propenes
Author:
Affiliation:
1. Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13 (Haus F), 81377 München, Germany
Funder
Deutsche Forschungsgemeinschaft
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.6b11003
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2. Lithium Compounds in Organic Synthesis
3. Stereochemical Aspects of Organolithium Compounds;Gawley, R. E.; Siegel, J. S., Eds.VHCA:Zürich, 2010.
4. Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position
5. How Microsolvation Numbers at Li Control Aggregation Modes, sp2-Stereoinversion, and NMR Coupling Constants 2JH,H of H2C═C in α-(2,6-Dimethylphenyl)vinyllithium
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1. Photoinduced ynamide structural reshuffling and functionalization;Nature Communications;2022-04-29
2. Why is cis / trans stereoinversion with Li + (THF) 4 migration across the phenyl ring of α-lithiostyrene accelerated by two ortho -methyl groups?;Tetrahedron;2018-04
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