Enantio- and Diastereodivergent Cyclopropanation of Allenes by Directed Evolution of an Iridium-Containing Cytochrome-Reference-Cited by-同舟云学术

Enantio- and Diastereodivergent Cyclopropanation of Allenes by Directed Evolution of an Iridium-Containing Cytochrome

Published:2024-01-08 Issue:3 Volume:146 Page:1819-1824
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Bloomer Brandon J.¹²,Joyner Isaac A.¹²,Garcia-Borràs Marc³^ORCID,Hu Derek B.¹,Garçon Martí¹²^ORCID,Quest Andrew¹,Ugarte Montero Consuelo¹,Yu Isaac F.¹^ORCID,Clark Douglas S.⁴⁵^ORCID,Hartwig John F.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of California, Berkeley, California 94720, United States

2. Division of Chemical Sciences, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

3. Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Girona 17003, Spain

4. Molecular Biophysics and Integrated Bioimaging, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

5. Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720, United States

Funder

Ministerio de Ciencia e Innovaci?n

Ag?ncia de Gesti? d'Ajuts Universitaris i de Recerca

National Institute of General Medical Sciences

National Science Foundation

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.3c13011

Reference14 articles.

1. α-(Methylenecyclopropyl)glycine from Litchi seeds

2. Synthesis of Methylene- and Alkylidenecyclopropane Derivatives

3. Rhodium-Mediated Enantioselective Cyclopropanation of Allenes

4. Substituent effects on rates of rhodium-catalyzed allene cyclopropanation

5. Highly Regio- and Stereoselective Synthesis of Alkylidenecyclopropanes via Ru(II)-Pheox Catalyzed Asymmetric Inter- and Intramolecular Cyclopropanation of Allenes

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