The Development of Scalemic Multidentate Niobium Complexes as Catalysts for the Highly Stereoselective Ring Opening of meso-Epoxides and meso-Aziridines

Author:

Arai Kenzo1,Lucarini Simone1,Salter Matthew M.1,Ohta Kentaro1,Yamashita Yasuhiro1,Kobayashi Shū1

Affiliation:

1. Contribution from the Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science Technology Agency (JST), Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference85 articles.

1. Catalytic Enantioselective CC Coupling—Allyl Transfer and Mukaiyama Aldol Reaction

2. For recent monographs on the chemistry of expoxides and aziridines see (a) Rao, A. S.Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press:  Oxford, U.K., 1991; Vol. 7, p 357. (b) Jacobsen, E. N.; Wu, M. H.Comprehensive Asymmetric Catalysis;Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer-Verlag:  Heidelberg, Germany, 1999; Vol. III, Chapter 35. (c) McCoull, W.; Davis, F. A.Synthesis2000, 1347. (d) Sweeny, J. B.Chem. Soc. Rev.2002,31, 247. (e) Pineschi, M.Eur. J. Org.Chem.2006, 4979.

3. Lanthanide(III) trifluoromethanesulfonates as extraordinarily effective new catalysts for the aminolysis of 1,2-epoxides

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