Mechanistic Insight into the Photoredox-Nickel-HAT Triple Catalyzed Arylation and Alkylation of α-Amino Csp3

Mechanistic Insight into the Photoredox-Nickel-HAT Triple Catalyzed Arylation and Alkylation of α-Amino Csp3–H Bonds

Published:2020-09-09 Issue:40 Volume:142 Page:16942-16952
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Maity Bholanath¹^ORCID,Zhu Chen¹^ORCID,Yue Huifeng¹^ORCID,Huang Long²^ORCID,Harb Moussab¹^ORCID,Minenkov Yury³^ORCID,Rueping Magnus¹^ORCID,Cavallo Luigi¹^ORCID

Affiliation:

1. King Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC), Thuwal, 23955-6900 Saudi Arabia

2. Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany

3. N. N. Semenov Federal Research Center for Chemical Physics RAS, Kosygina Street 4, 119991 Moscow, Russia

Funder

King Abdullah University of Science and Technology

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.0c05010

Reference60 articles.

1. From Noble Metal to Nobel Prize: Palladium-Catalyzed Coupling Reactions as Key Methods in Organic Synthesis

2. Recent Advances in C–H Functionalization

3. 2005 Nobel Prize in Chemistry. Development of the Olefin Metathesis Method in Organic Synthesis

4. Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

5. Metal‐Catalyzed Cross‐Coupling Reactions

Cited by 74 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. C(sp ³)–H trifluoromethylation of pyrrolidine by [W ₁₀O ₃₂] ⁴⁻/copper synergetic photocatalysis: Theoretical investigation of reactivity and regioselectivity;Polyoxometalates;2024-12

2. Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization;Chemical Reviews;2024-08-08

3. Thermodynamic H-Abstraction Abilities of Nitrogen Centered Radical Cations as Potential Hydrogen Atom Transfer Catalysts in Y–H Bond Functionalization;ACS Omega;2024-06-04

4. Nucleophilic Aliphatic Substitution 2020;Organic Reaction Mechanisms Series;2024-03-15

5. Leveraging the Redox Promiscuity of Nickel To Catalyze C–N Coupling Reactions;The Journal of Organic Chemistry;2024-01-17