Isolation of a Homoleptic Non-oxo Mo(V) Alkoxide Complex: Synthesis, Structure, and Electronic Properties of Penta-tert-Butoxymolybdenum-Reference-Cited by-同舟云学术

Isolation of a Homoleptic Non-oxo Mo(V) Alkoxide Complex: Synthesis, Structure, and Electronic Properties of Penta-tert-Butoxymolybdenum

Published:2020-08-27 Issue:38 Volume:142 Page:16392-16402
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Hillenbrand Julius¹^ORCID,van Gastel Maurice¹^ORCID,Bill Eckhard²^ORCID,Neese Frank¹^ORCID,Fürstner Alois¹^ORCID

Affiliation:

1. Max-Planck-Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany

2. Max-Planck-Institute for Chemical Energy Conversion, 45470 Mülheim/Ruhr, Germany

Funder

Max-Planck-Gesellschaft

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

http://pubs.acs.org/doi/pdf/10.1021/jacs.0c07073

Reference97 articles.

1. Neue Untersuchungen �ber die Chloride des Molybd�ns

2. Three New Polymorphic Forms of Molybdenum Pentachloride

3. Ferromagnetic Spin-1/2 Dimers with Strong Anisotropy in MoCl5

4. Black-crystalline MoCl5 is moisture sensitive and should be kept under inert atmosphere; because hydrolysis, which leads to the appearance of a greenish color, is rather slow, the compound can be manipulated in air for short periods of time.

5. Polymerization of Benzene to p-Polyphenyl by Molybdenum Pentachloride1

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