Nucleophilic Attack in Methoxycarbenes: Heterolytic Cleavage of the Carbon (sp3)–Oxygen Bond versus Aminolysis
Author:
Affiliation:
1. Departamento de Quı́mica Inorgánica and ‡Departamento de Quı́mica Fı́sica, Universidad de Vigo, Campus Universitario, E-36310 Vigo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om400565c
Reference40 articles.
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3. Transition metal-carbene complexes
4. MO calculations on metal carbene complexes and metal acyl complexes. The importance of the LUMO in determining the site of nucleophilic attack
5. Functionalised alkenylcarbene metal complexes (M=Ru, W, Cr) by activation of propargyl alcohol derivatives
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