Novel tert-Butyl Migration in Copper-Mediated Phenol Ortho-Oxygenation Implicates a Mechanism Involving Conversion of a 6-Hydroperoxy-2,4-cyclohexadienone Directly to an o-Quinone-Reference-Cited by-同舟云学术

Novel tert-Butyl Migration in Copper-Mediated Phenol Ortho-Oxygenation Implicates a Mechanism Involving Conversion of a 6-Hydroperoxy-2,4-cyclohexadienone Directly to an o-Quinone

Published:2000-07-20 Issue:16 Volume:65 Page:4804-4809
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Mandal Subrata¹,Macikenas Dainius¹,Protasiewicz John D.¹,Sayre Lawrence M.¹

Affiliation:

1. Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106-7078

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo991625m

Reference29 articles.

1. Structure and biogenesis of topaquinone and related cofactors

2. Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction

3. The oxidation of phenols with copper-amine catalysts and its relation to the mode of action of tyrosinase: I. The catalytic oxidation of monohydric phenols to orthoquinone derivatives

4. Oxidative cleavage reactions of catechol and phenol to monoester of cis,cis,-muconic acid with the oxidizing systems of O2/CuCl, KOH/CuCl2

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