DFT-Based Mechanism for the Unexpected Formation of Dienes in the PtCl2 Isomerization of Propargylic Acetates: Examples of Inhibition of the Rautenstrauch Process
Author:
Affiliation:
1. Laboratorio de Resonancia Magnética, Instituto de Investigaciones Biomédicas (CSIC), C/Arturo Duperier 4, 28029 Madrid, Spain, and Laboratorio de Radicales Libres, IQOG (CSIC), C/Juan de la Cierva 3, 28006 Madrid, Spain
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo0622983
Reference54 articles.
1. Electrophilic Activation and Cycloisomerization of Enynes: A New Route to Functional Cyclopropanes
2. Cyclizations of Enynes Catalyzed by PtCl2 or Other Transition Metal Chlorides: Divergent Reaction Pathways
3. Enyne Metathesis (Enyne Bond Reorganization)
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