Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an Unusual <i>S</i> = 3/2 Ground State that Promotes N-Group and Hydrogen Atom-Transfer Reactions with Exogenous Substrates-Reference-Cited by-同舟云学术

Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an Unusual S = 3/2 Ground State that Promotes N-Group and Hydrogen Atom-Transfer Reactions with Exogenous Substrates

Published:2023-11-24 Issue:48 Volume:145 Page:26106-26121
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Yang Jindou¹^ORCID,Tripodi Guilherme L.²,Derks Max T. G. M.²,Seo Mi Sook¹,Lee Yong-Min¹^ORCID,Southwell Kendal W.³,Shearer Jason³^ORCID,Roithová Jana²^ORCID,Nam Wonwoo¹⁴^ORCID

Affiliation:

1. Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea

2. Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, Nijmegen 6525 AJ, The Netherlands

3. Department of Chemistry, Trinity University, San Antonio, Texas 78212, United States

4. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Funder

Division of Chemistry

National Research Foundation of Korea

National Institutes of Health

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.3c08117

Reference146 articles.

1. 3d-transition metal catalyzed C–H to C–N bond formation: An update

2. Nitrene transfer catalysts for enantioselective C–N bond formation

3. Controlling Radical-Type Single-Electron Elementary Steps in Catalysis with Redox-Active Ligands and Substrates

4. Iron- and cobalt-catalyzed C(sp3)–H bond functionalization reactions and their application in organic synthesis

5. Mechanistic dichotomies in redox reactions of mononuclear metal–oxygen intermediates

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