Molecular Insights into the Spontaneous Generation of Cl<sub>2</sub>O in the Reaction of ClONO<sub>2</sub> and HOCl at the Air

Molecular Insights into the Spontaneous Generation of Cl₂O in the Reaction of ClONO₂ and HOCl at the Air–Water Interface

Published:2023-07-31 Issue:31 Volume:145 Page:17478-17484
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Wan Zhengyi¹,Zhu Chongqin²,Francisco Joseph S.¹³^ORCID

Affiliation:

1. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States

2. College of Chemistry, Key Laboratory of Theoretical & Computational Photochemistry of Ministry of Education, Beijing Normal University, Beijing 100190, People’s Republic of China

3. Department of Earth & Environmental Science, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.3c06527

Reference40 articles.

1. On the depletion of Antarctic ozone

2. Antarctic Stratospheric Chemistry of Chlorine Nitrate, Hydrogen Chloride, and Ice: Release of Active Chlorine

3. Reaction of Chlorine Nitrate with Hydrogen Chloride and Water at Antarctic Stratospheric Temperatures

4. Formation of chemically active chlorine compounds by reactions of atmospheric NaCl particles with gaseous N2O5 and ClONO2

5. Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures

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