Computational Design and Experimental Validation of Enzyme Mimicking Cu-Based Metal–Organic Frameworks for the Reduction of CO<sub>2</sub> into C<sub>2</sub> Products: C–C Coupling Promoted by Ligand Modulation and the Optimal Cu

Computational Design and Experimental Validation of Enzyme Mimicking Cu-Based Metal–Organic Frameworks for the Reduction of CO₂ into C₂ Products: C–C Coupling Promoted by Ligand Modulation and the Optimal Cu–Cu Distance

Published:2023-09-25 Issue:39 Volume:145 Page:21442-21453
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Mao Xin¹,Gong Wanbing²,Fu Yang³,Li Jiayi²,Wang Xinyu²,O’Mullane Anthony P.¹^ORCID,Xiong Yujie²^ORCID,Du Aijun¹^ORCID

Affiliation:

1. School of Chemistry and Physics and Centre for Materials Science, Queensland University of Technology, Gardens Point Campus, Brisbane 4001, Australia

2. Hefei National Research Center for Physical Sciences at the Microscale, School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026, China

3. Institute of Photoelectronic Thin Film Devices and Technology, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research, Centre of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Storage Centre, Nankai University, Tianjin 300350, China

Funder

Australian Research Council

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.3c07108

Reference60 articles.

1. Recent Advances in CO2 Reduction Electrocatalysis on Copper

2. Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

3. Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst