Synthesis of the First C-2 Cyclopalladated Derivatives of 1,3-Bis(2-pyridyl)benzene. Crystal Structures of [Hg(N-C-N)Cl], [Pd(N-C-N)Cl], and [Pd2(N-C-N)2(μ-OAc)]2[Hg2Cl6]. Catalytic Activity in the Heck Reaction-Reference-Cited by-同舟云学术

Synthesis of the First C-2 Cyclopalladated Derivatives of 1,3-Bis(2-pyridyl)benzene. Crystal Structures of [Hg(N-C-N)Cl], [Pd(N-C-N)Cl], and [Pd2(N-C-N)2(μ-OAc)]2[Hg2Cl6]. Catalytic Activity in the Heck Reaction

Published:2004-12-03 Issue:1 Volume:24 Page:53-61
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Soro Barbara¹,Stoccoro Sergio¹,Minghetti Giovanni¹,Zucca Antonio¹,Cinellu Maria Agostina¹,Gladiali Serafino¹,Manassero Mario¹,Sansoni Mirella¹

Affiliation:

1. Dipartimento di Chimica, Università di Sassari, Via Vienna 2, I-07100 Sassari, Italy, and Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università di Milano, Centro CNR, Via Venezian 21, I-20133 Milano, Italy

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om040102o

Reference64 articles.

1. Cyclopalladation to form planar tridentate [N–C–N]–intramolecular co-ordination systems involving pyridine donor groups, including ligand synthesis and X-ray structural studies

2. Divergent Behavior of Palladium(II) and Platinum(II) in the Metalation of 1,3-Di(2-pyridyl)benzene

3. Syntheses and Structures of New Luminescent Cyclometalated Palladium(II) and Platinum(II) Complexes: M(Bab)Cl, M(Br−Bab)Cl (M = Pd(II), Pt(II)), and Pd3Cl4(Tab)2 (Bab = 1,3-bis(7-azaindolyl)phenyl, Br−Bab = 1-Bromo-3,5-bis(7-azaindolyl)phenyl, Tab =1,3,5-tris(7-azaindolyl)phenyl)

4. Cyclometalated Compounds. XVII.1 The First Threefold Cyclopalladation of a Single Benzene Ring

5. Complexes with a Pincers. 2,6-Diphenylpyridine as Twofold-Deprotonated (C ? N ? C) terdentate ligand in C,C-trans-, and as mono-deprotonated (C ? N) chelate ligand in chiral C,C-cis-complexes of platinum(II) and palladium(II). Preliminary communication

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