Base-Catalyzed Decarboxylation of Mandelylthiamin: Direct Formation of Bicarbonate as an Alternative to Formation of CO2
Author:
Affiliation:
1. Davenport Chemical Laboratories, Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 3H6
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja310952a
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3. Alcohol-bicarbonate-water system. Structure-reactivity studies on the equilibriums for formation of alkyl monocarbonates and on the rates of their decomposition in aqueous alkali
4. Accelerating Unimolecular Decarboxylation by Preassociated Acid Catalysis in Thiamin-Derived Intermediates: Implicating Brønsted Acids as Carbanion Traps in Enzymes
5. Electrophilic Substitution at Saturated Carbon. XI. Steric Course of the Basecatalyzed Decarboxylation Reaction1
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