Low-Spin Hexacoordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes

Author:

Forshaw Adam P.1,Smith Jeremy M.1,Ozarowski Andrew2,Krzystek J.2,Smirnov Dmitry2,Zvyagin S. A.3,Harris T. David4,Karunadasa Hemamala I.5,Zadrozny Joseph M.6,Schnegg Alexander7,Holldack Karsten8,Jackson Timothy A.9,Alamiri Ahmad10,Barnes Diane M.10,Telser Joshua10

Affiliation:

1. Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, United States

2. National High Magnetic Field Laboratory (NHMFL), Florida State University, Tallahassee, Florida 32310, United States

3. Dresden High Magnetic Field Laboratory (HLD), Helmholtz-Zentrum Dresden-Rossendorf, D-01314 Dresden, Germany

4. Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States

5. Department of Chemistry, Stanford University, Stanford, California 94305, United States

6. Department of Chemistry, University of California, Berkeley, California 94720, United States

7. Helmholtz-Zentrum für Materialien und Energie, Institut für Silizium-Photovoltaik, D-12489 Berlin, Germany

8. Helmholtz-Zentrum für Materialien und Energie, Institut für Methoden und Instrumente der Forschung mit Synchrotronstrahlung, D-12489 Berlin, Germany

9. Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, United States

10. Department of Biological, Chemical and Physical Sciences, Roosevelt University, Chicago, Illinois 60605, United States

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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