Facile Reduction of Tungsten Halides with Nonconventional, Mild Reductants. I. Tungsten Tetrachloride: Several Convenient Solid-State Syntheses, a Solution Synthesis of Highly Reactive (WCl4)x, and the Molecular Structure of Polymeric Tungsten Tetrachloride
Author:
Affiliation:
1. Department of Chemistry, The University of Iowa, Iowa City, Iowa 52242
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9801286
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3. Preparation of octachloroditungstate(4-) and several of its derivatives
4. Preparation and characterization of sodium heptachloropentakis(THF)ditungstate(1-). A synthetically useful precursor for X3W.tplbond.WX3 compounds where X = CH2-tert-Bu, NMe2 and O-tert-Bu
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