Unexpected Synthesis of a Perfluoroacyl Complex, Cp*Ir(CO)(COC6F11)Br, by Direct Fluoroalkylation of a CO Ligand, and Elimination of Perfluorocyclohexene by Activation of a γ-C−F Bond-Reference-Cited by-同舟云学术

Unexpected Synthesis of a Perfluoroacyl Complex, Cp*Ir(CO)(COC6F11)Br, by Direct Fluoroalkylation of a CO Ligand, and Elimination of Perfluorocyclohexene by Activation of a γ-C−F Bond

Published:2011-02-18 Issue:6 Volume:30 Page:1744-1746
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Yuan Jian¹,Hughes Russell P.¹,Rheingold Arnold L.²

Affiliation:

1. Department of Chemistry, 6128 Burke Laboratory, Dartmouth College, Hanover, New Hampshire 03755, United States

2. Departments of Chemistry, University of California, San Diego, California 92093-0358, United States

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om200019d

Reference21 articles.

1. Conversion of Carbon–Fluorine Bonds α to Transition Metal Centers to Carbon–Hydrogen, Carbon–Carbon, and Carbon–Heteroatom Bonds

2. Carbonfluorine bond activation by platinum group metal complexes

3. Activation of C–F bonds using Cp*2ZrH2: a diversity of mechanisms

4. Recent Advances in C–F Bond Activation

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