Thiyl Radical-Mediated Cleavage of Allylic C−N Bonds: Scope, Limitations, and Theoretical Support to the Mechanism-Reference-Cited by-同舟云学术

Thiyl Radical-Mediated Cleavage of Allylic C−N Bonds: Scope, Limitations, and Theoretical Support to the Mechanism

Published:2004-09-11 Issue:39 Volume:126 Page:12343-12352
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Escoubet Stéphanie¹,Gastaldi Stéphane¹,Timokhin Vitaliy I.¹,Bertrand Michèle P.¹,Siri Didier¹

Affiliation:

1. Contribution from the Laboratoire de Chimie Moléculaire Organique, UMR 6517, Boite 562, Faculté des Sciences St Jérôme, Université d'Aix-Marseille III, Avenue Normandie-Niemen, 13397 Marseille Cedex 20, France, Department of Physical Chemistry, Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 3A Naukova Street, 79060, Lviv, Ukraine, and Laboratoire de Chimie Théorique et Modélisation Moléculaire, UMR 6517, Boite 521, Faculté des Sciences St Jérôme, Université de Provence, Avenue...

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja049859x

Reference79 articles.

1. On the use of silylated nucleophiles in the palladium catalysed deprotection of allylic carboxylates and carbamates.

2. Mild and selective palladium(0)-catalyzed deallylation of allylic amines. Allylamine and diallylamine as very convenient ammonia equivalents for the synthesis of primary amines

3. Selective deprotection of allyl amines using palladium

4. Deprotection of Allyl Groups with Sulfinic Acids and Palladium Catalyst

5. Reaction des chloroformiates sur les amines tertiaires: competition entre n-demethylation, desamination, n-debenzylation et n-desallylation

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