Joint Experimental and Theoretical Studies of the Mechanism for the Gas Phase Elimination Kinetics of Methyl 2,2-Dimethyl-3-hydroxypropionate
Author:
Affiliation:
1. Centro de Química, Instituto Venezolano de Investigaciones Científicas (IVIC), Apartado 21827, Caracas, Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Apartado 1020-A, Caracas, Venezuela
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp810649w
Reference25 articles.
1. Thermal decomposition of .beta.-hydroxy esters. Ethyl-3-hydroxy-3-methylbutanoate
2. Thermal decomposition of .beta.-hydroxy esters
3. Taylor, R.InAcid Derivatives;Patai, Saul, Ed. The Chemistry of Functional Group. Suplementary Volume B;Wiley:London, 1979; Chapter 15, pp859−914.
4. Holbrook, K. A.InVapor and Gas phase Reaction of Carboxylic Acids and their Derivatives;Patai, Saul, Ed. The Chemistry of Acid Derivatives.Volume 2;Wiley:London, 1992; Chapter 12, pp703−746.
5. The mechanism of thermal eliminations. Part 22. Rate data for pyrolysis of primary, secondary, and tertiary β-hydroxy alkenes, β-hydroxy esters, and β-hydroxy ketones. The dependence of transition-state structure for six-centre eliminations upon compound type
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