Substituent Effect on Reactivity of Triplet Excited State of 2,3-Diazabicyclo[2.2.1]hept-2-enes, DBH Derivatives: α C–N Bond Cleavage versus β C

Substituent Effect on Reactivity of Triplet Excited State of 2,3-Diazabicyclo[2.2.1]hept-2-enes, DBH Derivatives: α C–N Bond Cleavage versus β C–C Bond Cleavage

Published:2012-10-01 Issue:5 Volume:78 Page:1940-1948
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Abe Manabu¹²,Watanabe Shinji,Tamura Hiroshi,Boinapally Srikanth²,Kanahara Kousei,Fujiwara Yoshihisa

Affiliation:

1. Institute of Molecular Science, Okazaki 444-8787, Japan

2. CREST, JST, K’s Gobancho, 7, Gobancho, Chiyoda-ku, Tokyo 102-0076, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo3019472

Reference62 articles.

1. Intriguing double-inversion stereochemistry in the denitrogenation of 2,3-diazabicyclo[2.2.1]heptene-type azoalkanes: a model mechanistic study in physical organic chemistry

2. Computational Study on the Origin of the Stereoselectivity for the Photochemical Denitrogenation of Diazabicycloheptene

3. Diyl Trapping and Electroreductive Cyclization Reactions

4. The overlap component of the stereoelectronic factor. Remote control of stereogenicity transfer through the anisotropic influence of a ring

5. Mechanism of the thermal and photochemical decomposition of azoalkanes

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