Electrochemical and Structural Characterization of cis- and trans-[Cp(CO)Ru(μ-As(C6H5)2)]2, Isomers That Undergo Two-Electron-Transfer Oxidations

Author:

DiMaio Anthony-Joseph1,Rheingold Arnold L.1,Chin Teen T.1,Pierce David T.1,Geiger William E.1

Affiliation:

1. Departments of Chemistry, University of Delaware, Newark, Delaware 19716, and University of Vermont, Burlington, Vermont 05405

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference37 articles.

1. Geiger, W. E.; Connelly, N. G.Advances in Organometallic Chemistry; Stone, F. G. A., West, R., Eds.; Academic Press, Inc.  Orlando, FL, 1985; Vol. 24, pp 98−110.

2. Astruc, D.Electron-Transfer and Radical Processes in Transition MetalChemistry; VCH Publishers:  New York, 1995; pp 247 ff.

3. The dithiobis(tricarbonyliron) dianion: Improved preparation and new chemistry

4. Role of the metal-metal bond in transition-metal clusters. Phosphido-bridged diiron carbonyl complexes

5. Correlation of heterogeneous electron transfer rate with structural change and environmental factors in the two-electron oxidation of W2(CO)8(μ-SBz)22−

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