Improved Syntheses and Expanded Analyses of the Enantiomerically Enriched Chiral Cobalt Complexes Co(en)3I3 and Co(diNOsar)Br3

Author:

McClellan Michael J.1,Cass Marion E.1

Affiliation:

1. Department of Chemistry, Carleton College, Northfield, Minnesota 55057, United States

Funder

Division of Chemistry

Publisher

American Chemical Society (ACS)

Subject

Education,General Chemistry

Reference15 articles.

1. Angelici, R. J.Synthesis and Technique in Inorganic Chemistry,2nd ed.W. B. Saunders Company:Philadelphia, PA, 1977; pp71–802.

2. Girolami, G. S., Rauchfuss, T. B., Angelici, R. J.Synthesis and Technique in Inorganic Chemistry, A Laboratory Manual,3rd ed.University Science Books:Sausalito, CA, 1999; pp143–150.

3. Facile synthesis of a macrobicyclic hexaamine cobalt(III) complex based on tris(ethylenediamine)cobalt(III): An advanced undergraduate inorganic laboratory experiment

4. Synthesis of cobalt(III) "cage" complexes: A twist on an old theme in the inorganic laboratory

5. aPrior to optimization, tabulation of student data over 4 years: yields ranged from 3% to 80%, averaging 30%; enantiomeric excess values ranged from 50–70%.

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