Stereospecific CO Insertion into the Rhodium−Methyl σ Bond in [(Cp‘-P)Rh(CO)(Me)]BF4 and Deinsertion from [(Cp‘-P)Rh(COMe)I]:  Experimental Evidence for Methyl Migration

Author:

Kataoka Yasutaka1,Shibahara Atsushi1,Yamagata Tsuneaki1,Tani Kazuhide1

Affiliation:

1. Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference26 articles.

1. Yamamoto, A.Organotransition Metal Chemistry; Wiley:  New York, 1986:  p 246.

2. Collmann, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G.Principlesand Applications of Organotransition Metal Chemistry; University Science Books:  Mill Valley, CA, 1987:  p 360.

3. Recent fundamental studies on migratory insertion into metal-carbon bonds

4. Reactive Intermediates in the Photodecarbonylation of the Cyclopentadienyl and Indenyl Complexes CpFe(CO)2(C(O)CH3) and IndFe(CO)2(C(O)CH3) (Cp = η5-C5H5; Ind = η5-C9H7)

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